Thiophene For Synthesis MSDS

 

Section 1: Chemical Product and Company Identification

Product Name: Thiophene For Synthesis

Catalog Codes: SLT3487

CAS#: 108-98-5

RTECS: XM7350000

TSCA: TSCA 8(b) inventory: Thiophene For Synthesis

CI#: Not available.

Synonym: Thiofuran

Chemical Formula: C4H4S

 

Section 2: Composition and Information on Ingredients

Composition:

Name CAS # % by Weight

Thiophene For Synthesis 108-98-5 100

Toxicological Data on Ingredients: Thiophene For Synthesis: ORAL (LD50): Acute: 1400 mg/kg [Rat]. 420 mg/kg [Mouse].

 

Section 3: Hazards Identification

Potential Acute Health Effects:

Very hazardous in case of ingestion. Hazardous in case of skin contact (irritant, permeator), of eye contact (irritant), of

inhalation.

Potential Chronic Health Effects:

CARCINOGENIC EFFECTS: Not available. MUTAGENIC EFFECTS: Not available. TERATOGENIC EFFECTS: Not available.

DEVELOPMENTAL TOXICITY: Not available. The substance is toxic to blood, kidneys, the nervous system, liver, mucous

membranes. Repeated or prolonged exposure to the substance can produce target organs damage.

 

Section 4: First Aid Measures

Eye Contact: Check for and remove any contact lenses. Do not use an eye ointment. Seek medical attention.

Skin Contact:

After contact with skin, wash immediately with plenty of water. Gently and thoroughly wash the contaminated skin with running

water and non-abrasive soap. Be particularly careful to clean folds, crevices, creases and groin. Cover the irritated skin with an

emollient. If irritation persists, seek medical attention. Wash contaminated clothing before reusing.

Serious Skin Contact:

Wash with a disinfectant soap and cover the contaminated skin with an anti-bacterial cream. Seek immediate medical

attention.

Inhalation: Allow the victim to rest in a well ventilated area. Seek immediate medical attention.

Serious Inhalation:

Evacuate the victim to a safe area as soon as possible. Loosen tight clothing such as a collar, tie, belt or waistband. If

breathing is difficult, administer oxygen. If the victim is not breathing, perform mouth-to-mouth resuscitation. Seek medical

attention.

Ingestion:

Do not induce vomiting. Examine the lips and mouth to ascertain whether the tissues are damaged, a possible indication that

the toxic material was ingested; the absence of such signs, however, is not conclusive. Loosen tight clothing such as a collar,

tie, belt or waistband. If the victim is not breathing, perform mouth-to-mouth resuscitation. Seek immediate medical attention.

Serious Ingestion: Not available.

 

Section 5: Fire and Explosion Data

Flammability of the Product: Flammable.

Auto-Ignition Temperature: 395C (743F)

Flash Points: CLOSED CUP: 0.11C (32.2F).

Flammable Limits: LOWER: 1.5% UPPER: 12.5%

Products of Combustion: These products are carbon oxides (CO, CO2).

Fire Hazards in Presence of Various Substances: Flammable in presence of open flames and sparks.

Explosion Hazards in Presence of Various Substances:

Risks of explosion of the product in presence of mechanical impact: Not available. Risks of explosion of the product in

presence of static discharge: Not available.

Fire Fighting Media and Instructions:

Flammable liquid, insoluble in water. SMALL FIRE: Use DRY chemical powder. LARGE FIRE: Use water spray or fog. Never

direct a water jet in the container in order to prevent any splashing of the product which could cause spreading of the fire.

Special Remarks on Fire Hazards: Not available.

Special Remarks on Explosion Hazards: Not available.

 

Section 6: Accidental Release Measures

Small Spill: Absorb with an inert material and put the spilled material in an appropriate waste disposal.

Large Spill:

Toxic flammable liquid, insoluble or very slightly soluble in water. Keep away from heat. Keep away from sources of ignition.

Stop leak if without risk. Absorb with DRY earth, sand or other non-combustible material. Do not get water inside container.

Do not touch spilled material. Prevent entry into sewers, basements or confined areas; dike if needed. Eliminate all ignition

sources. Call for assistance on disposal.

 

Section 7: Handling and Storage

Precautions:

Keep away from heat. Keep away from sources of ignition. Ground all equipment containing material. Do not ingest. Do not

breathe gas/fumes/ vapour/spray. Wear suitable protective clothing In case of insufficient ventilation, wear suitable respiratory

equipment If ingested, seek medical advice immediately and show the container or the label. Avoid contact with skin and eyes

Storage:

Flammable materials should be stored in a separate safety storage cabinet or room. Keep away from heat. Keep away from

sources of ignition. Keep container tightly closed. Keep in a cool, well-ventilated place. Ground all equipment containing

material. A refrigerated room would be preferable for materials with a flash point lower than 37.8C (100F).

 

Section 8: Exposure Controls/Personal Protection

Engineering Controls:

Provide exhaust ventilation or other engineering controls to keep the airborne concentrations of vapors below their respective

threshold limit value. Ensure that eyewash stations and safety showers are proximal to the work-station location.

Personal Protection:

Splash goggles. Lab coat. Vapor respirator. Be sure to use an approved/certified respirator or equivalent. Gloves.

Personal Protection in Case of a Large Spill:

Splash goggles. Full suit. Vapor respirator. Boots. Gloves. A self contained breathing apparatus should be used to avoid

inhalation of the product. Suggested protective clothing might not be sufficient; consult a specialist BEFORE handling this

product.

Exposure Limits: Not available.

 

Section 9: Physical and Chemical Properties

Physical state and appearance: Liquid.

Odor: Benzene-like. (Slight.)

Taste: Not available.

Molecular Weight: 84.14 g/mole

Color: Clear Colorless.

pH (1% soln/water): Not applicable.

Boiling Point: 84.16C (183.5F)

Melting Point: 3.82C (38.9F)

Critical Temperature: Not available.

Specific Gravity: 1.1 (Water = 1)

Vapor Pressure: Not available.

Vapor Density: 2.9 (Air = 1)

Volatility: Not available.

Odor Threshold: Not available.

Water/Oil Dist. Coeff.: Not available.

Ionicity (in Water): Not available.

Dispersion Properties: Not available.

Solubility: Insoluble in cold water.

 

Section 10: Stability and Reactivity Data

Stability: The product is stable.

Instability Temperature: Not available.

Conditions of Instability: Not available.

Incompatibility with various substances: Not available.

Corrosivity: Non-corrosive in presence of glass.

Special Remarks on Reactivity: Not available.

Special Remarks on Corrosivity: Not available.

Polymerization: No.

 

Section 11: Toxicological Information

Routes of Entry: Dermal contact. Eye contact. Inhalation. Ingestion.

Toxicity to Animals: Acute oral toxicity (LD50): 420 mg/kg [Mouse].

Chronic Effects on Humans: The substance is toxic to blood, kidneys, the nervous system, liver, mucous membranes.

Other Toxic Effects on Humans:

Very hazardous in case of ingestion. Hazardous in case of skin contact (irritant, permeator), of inhalation.

Special Remarks on Toxicity to Animals: Not available.

Special Remarks on Chronic Effects on Humans: Not available.

Special Remarks on other Toxic Effects on Humans: Not available.

 

Section 12: Ecological Information

Ecotoxicity: Not available.

BOD5 and COD: Not available.

Products of Biodegradation:

Possibly hazardous short term degradation products are not likely. However, long term degradation products may arise.

Toxicity of the Products of Biodegradation: The products of degradation are more toxic.

Special Remarks on the Products of Biodegradation: Not available.

 

Section 13: Disposal Considerations

Waste Disposal:

 

Section 14: Transport Information

DOT Classification: Class 3: Flammable liquid.

Identification: : Thiophene For Synthesis : UN2414 PG: II

Special Provisions for Transport: Not available.

 

Section 15: Other Regulatory Information

Federal and State Regulations:

Pennsylvania RTK: Thiophene For Synthesis Florida: Thiophene For Synthesis Massachusetts RTK: Thiophene For Synthesis New Jersey: Thiophene For Synthesis TSCA 8(b)

inventory: Thiophene For Synthesis

Other Regulations: OSHA: Hazardous by definition of Hazard Communication Standard (29 CFR 1910.1200).

Other Classifications:

WHMIS (Canada):

CLASS B-2: Flammable liquid with a flash point lower than 37.8C (100F). CLASS D-1B: Material causing immediate and

serious toxic effects (TOXIC).

DSCL (EEC):

R11- Highly flammable. R36/38- Irritating to eyes and skin. R48/22- Harmful: danger of serious damage to health by prolonged

exposure if swallowed.

HMIS (U.S.A.):

Health Hazard: 2

Fire Hazard: 3

Reactivity: 0

Personal Protection: h

National Fire Protection Association (U.S.A.):

Health: 2

Flammability: 3

Reactivity: 0

Specific hazard:

Protective Equipment:

Gloves. Lab coat. Vapor respirator. Be sure to use an approved/certified respirator or equivalent. Wear appropriate respirator

when ventilation is inadequate. Splash goggles.

 

Section 16: Other Information

References: Not available.

Other Special Considerations: Not available.

Created: 10/10/2005 12:04 AM

Last Updated: 11/06/2008 12:00 PM